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Additionally, GSH shifts the melanogenesis pathway away from eumelanin (the darker brown/black pigment) toward pheomelanin (the lighter red/orange pigment) by interacting with dopaquinone intermediates in the Raper-Mason pathway

Similar biphasic kinetics, although a 100-fold slower, were reported for the GSSG-dependent oxidation of fusion constructs between rxYFP and a mono- or dithiol variant of ScGrx1 from yeast 31

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J Phys Chem 107:24152425

The Nrf2 activity remains suppressed under physiological conditions due to its degradation via ubiquitination and proteasomal pathways

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